preparation of hexanitrohexaazaisowurtzitane (hniw) nano particle by normal microemulsion based nonionic surfactant
نویسندگان
چکیده
the behavior of nanoscale energetic materials is quite different from micronsized energetic materials inmany ways. recently, some techniques such as sol-gel method, high speed air impaction and vacuum codeposition have been employed to obtain nanoscale energetic materials. however, only few attentionswere paid to nanoscale energetic materials because of the fabrication difficulty. in this paper, the simplepreparation of a nitramine 2,4,6,8,10,12 hexanitro 2,4,6,8,10,12 hexaazaiso wurtzitane (hniw) withnanometer size by microemulsion method is presented. the microemulsion systems contained tween80,2-propanol and n-butyl acetate as the oil phase. on the base of dls measurement average particle size is8 nm. the prepared nanoparticles are semispherical based on sem picture.
منابع مشابه
Preparation of Hexanitrohexaazaisowurtzitane (HNIW) Nano Particle by Normal Microemulsion Based Nonionic Surfactant
The behavior of nanoscale energetic materials is quite different from micronsized energetic materials in many ways. Recently, some techniques such as sol-gel method, high speed air impaction and vacuum codeposition have been employed to obtain nanoscale energetic materials. However, only few attentions were paid to nanoscale energetic materials because of the fabrication difficulty. In this pap...
متن کاملSurfactant Effects on Microemulsion-Based Nanoparticle Synthesis
The effect of the surfactant on the size, polydispersity, type of size distribution and structure of nanoparticles synthesized in microemulsions has been studied by computer simulation. The model simulates the surfactant by means of two parameters: the intermicellar exchange parameter, kex, related to dimer life time, and film flexibility parameter, f, related to interdroplet channel size. One ...
متن کاملSurfactant-free CO2-based microemulsion-like systems.
The presence of water-rich and water-lean nanodomains in a transparent, pressurized "water-acetone-CO2" mixture was revealed by Raman spectroscopy. This nano-structured liquid can be classified as a surfactant-free microemulsion-like system and has the capacity to dissolve hydrophobic compounds, such as ibuprofen, in the presence of large amounts of water. This finding opens new opportunities i...
متن کاملSugar-Ester Nonionic Microemulsion: Structural Characterization.
Surfactants containing sugar components and fatty acids satisfy the quality standards for food application. The food grade sugar ester in this study is a commercial sucrose monoester of stearic acid (abbreviated SES), the oil phase consists of a 1:1 mixture of n-tetradecane and l-butanol. The originally planned food grade oil, a medium chain triglyceride, is substituted by tetradecane because t...
متن کاملPreparation and Characterization of Functional Compounds Encapsulated Microemulsion with Nonionic Surfactants
Influence of hydrophobic chain lengths of surfactant, co-surfactant, oil and different surfactant to co-surfactant ratios on phase behavior of Tween/alcohol/alkane/H2O was investigated with pseudo-ternary phase diagrams. The total areas of the microemulsion (ME) regions were determined. The largest ME region was formed when the ratio of surfactant: co-surfactant was 2 : 1 (w/w). The capacity fo...
متن کاملStudy of the Cloud Point of Nonionic Surfactant and Nonionic-cationic Surfactant Mixture: Effect of Electrolytes
Clouding phenomenon generally occurs with nonionic surfactants when the temperature of the system is raised to a certain value. This critical temperature is termed the cloud point (CP). The aqueous solutions of nonionic surfactants show complex phase behaviour including liquid-liquid phase separation at this temperature. The cloud point of aqueous surfactant solutions is influenced by the prese...
متن کاملمنابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
international journal of nanoscience and nanotechnologyناشر: iranian nano society
ISSN 1735-7004
دوره 9
شماره 3 2013
کلمات کلیدی
میزبانی شده توسط پلتفرم ابری doprax.com
copyright © 2015-2023